Pembuatan Ekstrak Rhizophora mucronata Sebagai Bahan Baku Inhibitor Korosi Skala Lab dan Skala Aplikasi
DOI:
https://doi.org/10.30588/jeemm.v5i1.777Keywords:
inhibitor, ekstrak pekat, Rhizophora mucronata, skala lab, skala aplikasiAbstract
Pembuatan inhibitor dalam bentuk ekstrak pekat dari bahan organik pada skala lab telah banyak dilakukan, namun percobaan dalam skala aplikasi yang lebih besar jarang dilakukan. Bahan organik pembuatan ekstrak pekat dapat menggunakan daun bakau (Rhizopora mucronata) banyak ditemukan di daerah mangrove. Penelitian bertujuan untuk membandingkan proses pembuatan inhibitor berupa ekstrak pekat dari daun bakau skala lab dengan skala aplikasi yang lebih besar terkait waktu pemekatan, daya listrik yang digunakan, sifat fisik (berat jenis dan sifat warna), sifat fitokimia (alkaloid, flavonoid, saponin dan tannin) dari ekstrak pekat yang dihasilkan. Pada skala lab, 500 gram daun kering bakau, dilarutkan dalam 500 ml etanol 96%, setelah 2 hari filtrate disaring dan dipekatkan hingga menjadi 10 ml menggunakan rotary evaporator. Pada skala aplikasi 20 kali lebih besar dari skala lab dan proses pemekatan menggunakan kipas angin. Hasil penelitian menunjukkan bahwa proses pembuatan 10 ml ekstrak pekat skala lab menggunakan rotary evaporator memerlukan waktu 4 jam, dengan menghabiskan daya listrik sebesar 10,4 KWH. Ekstrak pekat memiliki berat jenis 0,958 dan sifat warna L* = 2,8, a* = 6,6 dan b* = 3,2. Sedangkan proses pembuatan 200 ml ekstrak pekat skala aplikasi yang lebih besar yang menggunakan kipas angin memerlukan waktu 72 jam, dengan menghabiskan daya listrik sebesar 3,6 KWH. Ekstrak pekat memiliki berat jenis 0,965 dan sifat warna L* = 6,8, a* = 17,4 dan b* = 8,8. Kedua cara ekstraksi memiliki komponen fitokimia yang sama, yaitu flavonoid, saponin dan tannin.References
Afanasyev, I., Orlova, E., & Feoktistov, D. (2015). Evaporation of Stationary Alcohol Layer in Minichannel Under Air Flow. EPJ Web of Conferences. 82. Doi: 10.1051/epjconf/20158201054.
Al-Qudah, M. A. (2011). Inhibition of copper corrosion by flavonoids in nitric acid. E-Journal of Chemistry, 8(1), 326–332. https://doi.org/10.1155/2011/543498.
Bahrin, N., N. Muhammad, N. Abdullah, B. Hj. A. Talip, S. Jusoh, & S. W. Theng. (2018). Effect of Processing Temperature on Antioxidant Activity of Ficus carica Leaves Extract. Journal of Science and technology. 10 (2), pp. 99-103.
Chigondo, M., & F. Chigondo. (2016). Recent Natural Corrosion Inhibitors for Mild Stell: An Overview. Journal of Chemistry. Doi: 10.1155/2016/6208937.
Gurrala, P., K. Katre, P., Balusamy, S., Banerjee, S., & Sahu, K. C. (2019). Evaporation of Ethanol-water Droplet at Different Substrate temperatures and Compositions. International Journal of Heat and Mass Transfer. 145. Doi: 10.1016/j.ijheatmasstransfer.2019.118770
Horvath, Z. H. (2016). The effect of Storage on the Colour of Paprika Powders with Added Oleoresin. Acta Univ. sapientiae Alimentaria, 9, pp. 50-59.
Ikeuba, A. I., Ita, B. I., Etiuma, R. A., Bassey, V. M., Ugi, B. U., Kporokpo, E. B., & Chemistry, A. (2015). Green Corrosion Inhibitors for Mild Steel in H 2 SO 4 Solution : Flavonoids of Gongronema latifolium. Chemical and Process Engineering Research, 34, 1–10.
Innocenzi, P., Malfatti, L., Costacurta, S., & Kidchob, T. (2008). Evaporation of Ethanol and Ethanol-Water Mixtures Studied by Time-resolved Infrared Spectroscopy. J. Phys. Chem. A. 112, pp. 6512-6516.
Keo, S., Meng, C., Oeung, S., Nov, V., Lon, S. A., Vichet, T., Va, T., Sourn, M., & Chea, S. (2017). Preliminary Phytochemical Screening of Selected Medicinal Plants of Cambodia. Asian Journal of Pharmacognosy; 1 (4), 16-23.
Kusmierek, E., & Chrzescijanska, E. (2015). Tannic acid as corrosion inhibitor for metals and alloys. Materials and Corrosion, 66(2), 169-174.https://doi.org/10.1002/maco.201307277.
Morguette, A. E. B., B. G., Bigotto, R. L., Varella, G. M., Andriani, L. F. A., Spoladori, P. M. L., Pereira, F. G., Andrare, C. A. C., Lancheros, C. V., Nakamura, N. S., Arakawa, M. L., Bruschi, J. C., Tomaz, A. A. S. G., Lonni, G., Kerbauy, E. R., Tavares, L. M., Yamauchi, & S. F. Y. Ogatta, (2019). Hydrogel Containing Oleoresin from Copaifera officinalis Presents Antibacterial Activity Against Streptococcus agalactiae. Frontiers in Microbiology, 10. doi: 10.3389/fmicb.2019.02806.
Oeung, S., Nov, V., Ung, H., Roum, K., Yin, V., & Keo, S. (2017). Phytochemical analysis of different extracts of leaves of Nicotiana tabacum L. of Cambodia. Asian Journal of Pharmacognosy Research. 1(3), pp 18-26.
Oh, W., & Kato, S. (2017). Study on the Effect of Evaporation and Condensation on the Underfloor Space of Japanese Detached House Using CFD Analysis. Energies. Doi: 10.3390/en10060789.
Ogunleye, O. O., A. O. Arinkoola, O. A. Eletta, O. O. Agbeda, Y. A.
Osho, A. F. Morakinyo, & J. O. Hamed. (2020). Green Corrosion Inhibition and Adsorption Characteristics of Luffa cylindrical Leaf Extract on Mild Steel in Hydrochloric Acid Environment. Heliyon. Doi: 10.1016/j.heliyon.2020.e03205.
Okafor, P. C., Ebiekpe, V. E., Azike, C. F., Egbung, G. E., Brisibe, E. A., & Ebenso, E. E. (2012). Inhibitory action of artemisia annua extracts and artemisinin on the corrosion of mild steel in HOsolution. International Journal of Corrosion, 2012. https://doi.org/10.1155/2012/768729.
Rani, B. E. A., & Basu, B. B. J. (2012). Green Inhibitors for Corrosion Protection of Metals and Alloys: an Overview. International Journal of Corrosion, doi: 10.1155/2012/380217.
Riquelme, N., & S.Matiacevich. (2017). Characterization and Evaluation of Some Properties of Oleoresin from Capsicum annuum var. cacho de cabra. Journal of Food, 15(3), pp. 344-351.
Salhi, A., Bouyanzer, A., Chetouani, A., El Ouariachi, E., Zarrouk, A., Hammouti, B.,desjobert, J.M., & Costa, J. (2017). Chemical Composotion, Antioxidant and Corrosion Activities of Mentha suaveolens, JMES, 8(5), pp. 1718-1728.
Sanni, O., O. S. I. Fayomi, & A. P. I. Popoola. (2019). Eco-friendly Inhibitors for Corrosion Protection of Stainless Stell: an Overview. International Conference on Engineering for Sustainable World. Doi: 10.1088/1742-6596/1378/4/042047.
Segura, L. I., V. O., Salvadori, & S. M. Goni. (2017). Characterization of Liquid food Colour from Digital Images. International Journal of Food Properties, 20, S1, pp. S467-S477.
Singh, A., Ebenso, E. E., & Quraishi, M. A. (2012). Corrosion inhibition of carbon steel in HCl solution by some plant extracts. International Journal of Corrosion, 2012. https://doi.org/10.1155/2012/897430.
Sun, C., Z. Wu, Z. Wang, & H. Zhang. (2015). Effect of Ethanol/water Solvent on Phenolic Profiles and Antioxidant Properties of Beijing Propolis Extracts. Evidence-Based Complementary and Alternative Medicine. Doi: 10.1155/2015/595393.
Surya, S., & Hari, N. (2017). Studies on preliminary phytochemical analysis of some true mangrove species in Kerala. International Journal of Research in Pharmacy and Pharmaceutical Sciences, 2(3), 15–17. http://www.pharmacyjournal.in/archives/2017/vol2/issue3/2-3-12.
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